Synthesis of organometallic helicenes by simple combinations
“Helicene” is the name introduced by Newman in 1955, to describe the benzologues of phenanthrene in which the extra ortho -condensed rings give rise to a (regular) cylindrical helix. The pioneer work of Newman in this field cannot be overemphasized; his brillant synthesis and resolution of [6]helicene will remain as a landmark, for it opened […]