Category archives: Chemistry

The stabilizing effect of a binder for transition metal oxides to sustain water oxidation in acidic environments

The stabilizing effect of a binder for transition metal oxides to sustain water oxidation in acidic environments

CatalysisChemistryDIPC Advanced materialsMaterials

By DIPC

Global energy demand is expected to rise around 30% by 2040 according to the International Energy Agency (IEA). Hydrogen (H2) produced by the electrolysis of water, using renewable electricity, the so-called green hydrogen, has emerged as a promising energy vector to respond to this increasing energy demand with the potential to decarbonize transportation, heating, and […]

Efficient on-surface Ullmann-like reaction on poorly reactive surfaces

Efficient on-surface Ullmann-like reaction on poorly reactive surfaces

ChemistryDIPC Electronic PropertiesDIPC Interfaces

By DIPC

The way a particular reaction proceeds, described in terms of the steps involved, is called mechanism. The study of organic chemistry is, to a great extent, the study of reaction mechanisms and textbooks content both their description and their applications. But something has come to revolutionize the world of mechanisms: surface chemistry. On-surface synthesis is […]

Crosslinking pectin for the simultaneous removal of multiple pollutants from water

Crosslinking pectin for the simultaneous removal of multiple pollutants from water

Chemical engineeringChemistryDIPC Polymers

By DIPC

Chemical contamination of water bodies on one hand, and water shortages due to overexploitation on the other, have increased the need for effective and efficient water treatment and decontamination processes. Two important aspects need to be taken into consideration to define what is an “effective and efficient” treatment. First, as current methods of removing pathogens […]

Sensitive on-site testing for PFAS in water samples

Sensitive on-site testing for PFAS in water samples

Chemistry

By César Tomé

Polyfluoroalkyl substances (PFAS), a family of highly fluorinated substances, represent a danger for humans and the environment. Particularly problematic members of this family, such as perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) appear to cause organ damage and cancer, as well as disrupting the endocrine system. Researchers have now introduced a new method for an […]

XIX, a new phase of high-density, ultra-hot water ice

XIX, a new phase of high-density, ultra-hot water ice

ChemistryPhysics

By César Tomé

Voyager II, a NASA solar system exploration spacecraft launched in 1977, measured highly unusual magnetic fields around Uranus and Neptune. Scientists considered exotic states of so-called superionic ice as a possible explanation due to these states’ increased electrical conductivity. A new work demonstrates the existence of the previously undiscovered Ice XIX phase. It shows that […]

Highly efficient, durable, and economically competitive hydrogen evolution electrocatalyst

Highly efficient, durable, and economically competitive hydrogen evolution electrocatalyst

CatalysisChemistryDIPC Advanced materials

By DIPC

Global energy demand is expected to rise around 30% by 2040 according to the International Energy Agency (IEA). Hydrogen (H2) produced by the electrolysis of water, using renewable electricity, the so-called green hydrogen, has emerged as a promising energy vector to respond to this increasing energy demand with the potential to decarbonize transportation, heating, and […]

Light-controled deracemization

Light-controled deracemization

CatalysisChemistry

By César Tomé

Just like our hands, certain organic molecules relate to each other like an image and its reflection – a phenomenon that chemists call “chirality” or “handedness”. The two mirror images of the same molecule, namely both enantiomers, often possess different biological properties. This is key, for example, for drug discovery, as many times only one […]

A new way to rationally design anti-Kasha emitters

A new way to rationally design anti-Kasha emitters

ChemistryDIPC Computational and Theoretical Chemistry

By DIPC

Light emission (fluorescence or phosphorescence) in organic molecules, in the vast majority of cases, proceeds from the lowest energy excited state irrespective of the excitation energy used. This is known as the Kasha’s rule, which states that most of the molecules are emissive from the lowest energy, same (ground state) spin multiplicity, S1 excited state […]

Tracking C–H bond activation with unprecedented resolution

Tracking C–H bond activation with unprecedented resolution

CatalysisChemistry

By César Tomé

C-H bond The emission of methane, a highly potent greenhouse gas, is escalating due to livestock farming and the ongoing thawing of permafrost. Converting methane and longer alkanes into more benign and valuable chemicals presents an opportunity to mitigate these hazards while providing a vast resource for the chemical industry. Nevertheless, the conversion of methane […]