Transition metal dichalcogenides (TMDs) are layered compounds which can be thinned down to the single-layer limit. While mechanical exfoliation generates atomically thin TMD flakes possessing an area of a few square microns, chemical and physical methods provide high-quality monolayers on large-area substrates, which are suitable for actual technological applications. TMDs are a class of van […]
Chemistry • DIPC Computational and Theoretical Chemistry • Materials
If we are asked what a metal is, most likely we would think almost automatically in those elements that we see as lustrous solids, good conductors of heat and electricity, that tend to form positive ions, and with a particular chemical bond that keep metal atoms in place, the metallic bond. And all of this […]
We live on a planet that is commonly known as the blue planet. This is because more than 70% of its surface is covered by water. However, it is ironic that one of the biggest problems humanity will face in the coming decades is the scarcity of drinking water. Despite the large amount of water […]
Chemistry • DIPC Computational and Theoretical Chemistry • Materials
Nanothreads are one-dimensional nanomaterials composed of a primarily sp 3 hydrocarbon backbone, typically formed through the compression of small molecules to high pressures. In 2015, it was found that the slow room-temperature compression of benzene produced crystalline , one-dimensional polymers composed of diamond-like bonds. These diamondoid materials that border nanotubes and polymers are predicted to […]
A cement is any of various substances used for bonding or setting to a hard material. A popular one, Portland cement, is a mixture of calcium silicates and aluminates made by heating limestone (CaCO3) with clay (that contains aluminosilicates) in a kiln. The product is then ground to a fine powder. When Portland cement is […]
An atomic state in which two spin angular momenta of electrons cancel each other, resulting in zero net spin, is called a singlet. If the angular momenta combine to give a total non-zero spin, then that state is called a triplet. A triplet state usually has lower, sometimes substantially lower, energy than a singlet. Importantly […]
We live in a time when scientific applications are growing by leaps and bounds. This exponential growth has been possible, among other tools, thanks to the application of nanotechnology. There is something that nanotechnology has taught us: In science, size matters. When studying matter at nanometric levels, we find that the properties are completely different […]
Electrons do not move around nuclei in defined curved orbits. Our current understanding of how electrons are to be found in atoms and molecules is based on clouds of probability called orbitals as it is not possible to give a definite path for an electron. Thus, an orbital is a region in which an electron […]
Catalysis-based approaches for the activation of anticancer rely on the use of metal catalysts capable of deprotecting inactive precursors of organic drugs or transforming key biomolecules available in the cellular environment. Nevertheless, the efficiency of most of the schemes described so far is rather low, limiting the benefits of catalytic amplification as a strategy for […]
The advent of on-surface chemistry under vacuum has vastly increased our capabilities to synthesize carbon nanomaterials with atomic precision. Among the types of target structures that have been synthesized by these means, one-dimensional graphene nanoribbons (GNRs) have probably attracted the most attention, and for a good reason: t he enormous tunability of GNRs’ electronic properties […]