Category archives: DIPC Electronic Properties

Organic compounds of sulphur that contain the group -S- linked to two hydrocarbons are known as thioethers. This alternative name to sulphides comes from the fact that they are analogues of ethers in which the oxygen is replaced by a sulphur; thioethers are generally more reactive than ethers, though. The formation of thioether structures increases […]

At the nanoscale, even the most basic quantum size effect, the induction of semiconducting gaps by electron confinement, requires ultimate precision. The case of graphene is a dramatic example, where deviations of a single atom in width can induce dramatic variations of the gap. As a consequence, local defects or variations in width can severely […]

One feature of supramolecular chemistry is that of self-assembly, in which the structure forms spontaneously as a consequence of the nature of the molecules. Weak non-covalent bonds are fundamental for designing self-assembled organic structures with potentially high responsiveness to mechanical, light, and thermal stimuli. The contributions of multiple weak interactions control the ability of the […]

As candidates for high-density data storage and quantum computation, magnetic transition metal complexes have attracted extensive attention. It has been established that the atomic surroundings of the magnetic ions play a significant role and govern the magnetism of these magnetic complexes. One feature in particular, magnetic anisotropy, which describes the preferential orientation of the magnetic […]

A catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change. The study of enzymes has provided us many of the prototypical concepts of catalysis, including the idea that a catalyst lowers the barrier to reaction and thereby accelerates the approach to chemical equilibrium, without altering […]

One-dimensional metal−organic chains often possess a complex magnetic structure, susceptible to modification by alteration of their chemical composition. The possibility to tune their magnetic properties provides an interesting playground to explore quasi-particle interactions in low-dimensional systems. These systems have potential applications in the fabrication of nanodevices for spin sensing, spintronics, quantum computing based on the […]

Graphene is an exceptional material with attractive properties to explore fundamental physics and for use in technological applications. While ideal graphene is non-magnetic, custom-shaped graphene nanostructures can be designed to exhibit complex magnetic phenomenology, with promising possibilities for a new generation of nanoscale spintronics devices. In fact, graphene π magnetism is more delocalized and isotropic […]

An atomic projectile colliding with a surface at kinetic energies in the thermal or hyperthermal range interacts with and is reflected by the electronic density well in front of the first layer of target atoms, and it is generally accepted that the repulsive interaction potential is proportional to the density of electrons extending outside the […]

Graphene nanoribbons (GNRs), are strips of graphene with ultra-thin width (<50 nm). Graphene ribbons were introduced as a theoretical model by Mitsutaka Fujita and coauthors to examine the edge and nanoscale size effect in graphene. Now, a team of researchers reports the generation of net spins on chiral GNRs (chGNRs) by ketone functionalization. GNRs are […]

When talking about molecules, “open shell” signifies that there are unpaired electrons. In terms of molecular orbital theory, it means that some molecular orbitals are singly occupied. Organic open-shell compounds are extraordinarily attractive materials for their use in molecular spintronics. In spintronics, new memory and logic devices are being developed based on the use of […]