Category archives: Chemistry

The morphogenetic mechanism of different biomorphs is independent of pH

The morphogenetic mechanism of different biomorphs is independent of pH

ChemistryDIPC Advanced materialsDIPC Interfaces

By DIPC

The bottom-up design of hierarchically organized nanostructures is a powerful strategy to achieve new materials with innovative functionalities. To a large extent, this approach takes inspiration from the ability of living organisms to engineer hybrid nanocomposites both for structural and functional purposes. Intense research has been dedicated to synthesizing biologically inspired textures and shapes mimicking […]

New design boosts performance in radical-based OLEDs

New design boosts performance in radical-based OLEDs

ChemistryDIPC Computational and Theoretical Chemistry

By DIPC

The development of luminescent organic radicals has resulted in materials with excellent optical properties for near-infrared (NIR) emission, like organic light-emitting diodes (OLEDs). Light generation in this range could be used for healthcare diagnosis and treatment to surveillance, communications and other security applications. Although an external quantum efficiency greater than 20% in electroluminescence has been […]

Investigating the fundamental stages of the CO oxidation reaction using a kinked Pt crystal

Investigating the fundamental stages of the CO oxidation reaction using a kinked Pt crystal

CatalysisChemistryDIPC Interfaces

By DIPC

Carbon monoxide (CO) oxidation (2CO + O2 → CO2) on platinum (Pt) group metal surfaces is the model heterogeneous gas/surface catalytic reaction. Pt itself is of the upmost importance as a catalyst for car exhaust cleaning or for the water gas shift reaction, whereas Pt crystal surfaces are model systems for investigating the catalytic CO […]

Synthesis of organometallic helicenes by simple combinations

Synthesis of organometallic helicenes by simple combinations

ChemistryDIPC BiochemistryMaterials

By DIPC

“Helicene” is the name introduced by Newman in 1955, to describe the benzologues of phenanthrene in which the extra ortho -condensed rings give rise to a (regular) cylindrical helix. The pioneer work of Newman in this field cannot be overemphasized; his brillant synthesis and resolution of [6]helicene will remain as a landmark, for it opened […]

Stable, high-energy-density and fast charging lithium-ion batteries

Stable, high-energy-density and fast charging lithium-ion batteries

ChemistryMaterials

By César Tomé

Convenient fast charging and energy density of lithium-ion batteries have long been considered a trade-off, which has hindered the widespread adoption of electric vehicles. A new process will help develop stable, high-energy-density lithium-ion batteries capable of fast charging. A crucial prerequisite for the widespread adoption of electric vehicles (EVs) is the enhancement of lithium-ion battery […]

Triple-decker antiaromatic π-stacking leads to a liquid crystal

Triple-decker antiaromatic π-stacking leads to a liquid crystal

Chemistry

By César Tomé

In organic chemistry, π-stacking systems are supramolecular structures that arise due to the dispersion force, a type of intermolecular noncovalent interaction. They are a common occurrence in nature. The stabilized structure of DNA is a very prominent example of a π-stacking system, and so are the arrangement of amino acids in certain proteins. Interestingly, π-stacking […]

A closer look at peptide fibril assemblies

A closer look at peptide fibril assemblies

BiochemistryBiologyChemistryNanotechnology

By César Tomé

A new imaging technique can give scientists a much closer look at fibril assemblies, stacks of peptides like amyloid beta, most notably associated with Alzheimer’s disease. These cross-β fibril assemblies are also useful building blocks within designer biomaterials for medical applications, but their resemblance to their amyloid beta cousins, whose tangles are a symptom of […]