Category archives: Nanotechnology

Most of the theories describing dynamical processes at surfaces rely on the validity of the adiabatic Born-Oppenheimer approximation. What does this mean? We have already seen that adsorption commonly is understood as the reversible binding of molecules and atoms from the gaseous or liquid phase on surfaces, mostly of highly porous adsorbent media. In chemisorption […]

Author: Roberto D’Agosta is an Ikerbasque Research Professor at ETSF and the Department of Materials Physics in the Faculty of Chemistry at the UPV/EHU in San Sebastian. Francesca Baletto, senior lecturer at King’s College London, read and commented the manuscript. Every single moment, nature exploits catalysis to make or improve specific chemical reactions. Catalysts facilitate […]

Many methods can be used to synthesise non-molecular inorganic solids. Some solids can be prepared by a variety of routes but others, especially those that are not thermodynamically stable, may be much more difficult to prepare and may require special methods. Non-molecular inorganic solids can also be prepared in various forms, as fibres, films, foams […]

Since the discovery that graphene, the two dimensional carbon allotrope, can be isolated and incorporated into electronic devices intense research efforts have been triggered. Driving forces usually mentioned behind the experimental and theoretical studies of graphene are the exceptional electronic properties, in particular the high electron mobilities, the long spin coherence lengths and the possibility […]

The electronic wave function of an n-electron molecule depends on 3n spatial and n spin coordinates. In a sense, the wave function of a many-electron molecule contains more information than is needed and is lacking in direct physical significance. This has prompted the search for methods that involve fewer variables than the wave function and […]

During the last decades, the electronics industry has been very successful in pushing forward the advancement of electronic building blocks, but the limit of silicon-based electronic devices especially in terms of miniaturization are almost reached. There are many ideas how to overcome this problem, for example, by adding functionality based on approaches originating from molecular […]

Modern organic industrial chemistry started when William Henry Perkin serendipitously synthesized mauveine in 1856 while he was attempting the total synthesis of quinine. Since then, thousands of new organic products have been created in the laboratory for industrial purposes. Among them, in 1913, an orange-red pigment was found, first known as Vat Orange 3 dye […]

What only a decades ago seemed impossible for chemists, determining the chemical structure of molecules directly from experimental images, is now routinely done. Not only that, the information about bond order, intermediates, and products of on-surface chemical reactions or charge distribution within molecules can also be quantified from those images. Two main techniques have made […]

Mimicking natural processes has been a recurrent strategy for the development of new technologies, from velcro to bullet trains. Thanks to the advances in scientific knowledge and technological tools achieved over the last decades, biologically inspired research has evolved from the macroscale to the nanoscale. This poses an interdisciplinary challenge, involving fields such as molecular […]

For centuries, metals were employed in optical applications only as mirrors and gratings. New vistas opened up in the late 1970s and early 1980s with the discovery of surface-enhanced Raman scattering and the use of surface plasmon (collective electronic oscillations at the surface of metals) resonances for sensing. However, it was not until the 1990s […]