Author archives: DIPC

Helium atom scattering can measure electron−phonon interaction properties of surfaces

Helium atom scattering can measure electron−phonon interaction properties of surfaces

Condensed matterMaterialsQuantum physics

By DIPC

Atom scattering at low energies has a long history as a useful probe of surface properties. The most common atomic projectiles are helium atoms formed into a monoenergetic beam directed toward the surface with energies in the thermal range, meaning kinetic energies less than 100 meV. From ordered surfaces the scattered spectra consist of sharp […]

Solvent-induced reversible clustering of gold nanoparticles

Solvent-induced reversible clustering of gold nanoparticles

ChemistryCondensed matterMaterialsNanotechnology

By DIPC

Many methods can be used to synthesise non-molecular inorganic solids. Some solids can be prepared by a variety of routes but others, especially those that are not thermodynamically stable, may be much more difficult to prepare and may require special methods. Non-molecular inorganic solids can also be prepared in various forms, as fibres, films, foams […]

Beyond the point-dipole approximation

Beyond the point-dipole approximation

Condensed matterMaterialsQuantum physicsTheoretical physics

By DIPC

The wave nature of light expresses itself in the propagation all over space, showing an intrinsic limitation to be localized beyond the so-called diffraction limit which is of the order of half the wavelength of the photons propagating. However when interacting with matter, light often gets reflected, diffracted, scattered or absorbed depending on the interactions […]

The flexibility of 2D silica

The flexibility of 2D silica

Condensed matterMaterialsNanotechnologyPhysics

By DIPC

Since the discovery that graphene, the two dimensional carbon allotrope, can be isolated and incorporated into electronic devices intense research efforts have been triggered. Driving forces usually mentioned behind the experimental and theoretical studies of graphene are the exceptional electronic properties, in particular the high electron mobilities, the long spin coherence lengths and the possibility […]

How to extract the interacting spectral function from a ground state DFT calculation

How to extract the interacting spectral function from a ground state DFT calculation

Condensed matterNanotechnologyPhysicsQuantum physicsTheoretical physics

By DIPC

The electronic wave function of an n-electron molecule depends on 3n spatial and n spin coordinates. In a sense, the wave function of a many-electron molecule contains more information than is needed and is lacking in direct physical significance. This has prompted the search for methods that involve fewer variables than the wave function and […]

Higher-order topological insulators

Higher-order topological insulators

Condensed matterMaterialsPhysicsTheoretical physics

By DIPC

Topological insulators are materials with special universal properties, which are protected against perturbations. Such properties are theoretically described by topology, a branch of mathematics concerned with the properties of geometrical objects that are unchanged by continuous deformations. Concretely, topological insulators are electronic materials that have a bulk band gap like an ordinary insulator but have […]

The forgotten fraction in semicrystalline semiconducting polymers

The forgotten fraction in semicrystalline semiconducting polymers

ChemistryCondensed matterMaterials

By DIPC

A class of materials of utmost fundamental and applied interest is that of semicrystalline polymers. Actually, all solid synthetic polymers are, in general, partly crystalline and partly amorphous. The degree of crystallinity depends on the polymer structure and on how the solid is prepared. Rapid cooling of the molten polymer favors formation of an amorphous […]

Temperature dependence of rare earth valence has nothing to do with Kondo temperature

Temperature dependence of rare earth valence has nothing to do with Kondo temperature

ChemistryCondensed matterQuantum physics

By DIPC

The scattering of conduction electrons in metals owing to impurities with magnetic moments is known as the Kondo effect, after Jun Kondo, who analysed the phenomenon in 1964. This scattering increases the electrical resistance and has the consequence that, in contrast to ordinary metals, the resistance reaches a minimum as the temperature is lowered and […]

Bioorthogonal catalytic activation of anticancer metal complexes

Bioorthogonal catalytic activation of anticancer metal complexes

BiomedicineChemistryCondensed matterDIPC Photochemistry

By DIPC

Metal complexes are typically regarded as catalysts that convert organic substrates into more valuable compounds; however, to date, catalytic transformations of metal complexes are practically unknown and represent a complete new way of thinking in catalysis. Their development can expand the scope of bioorthogonal chemical reactions to inorganic substances and metal-based prodrugs, fostering the creation […]

The multiscale nature of picocavities: a classical view to a quantum effect

The multiscale nature of picocavities: a classical view to a quantum effect

CFMDIPC

By DIPC

Progress in nanotechnology has allowed controlling the morphology of metallic nanoparticles at the nanometer and even subnanometer scale, triggering the development of various applications in plasmonics and nanooptics, such as in enhanced vibrational spectroscopy, improvement of energy absorption of solar cells, optoelectronic circuits, quantum optics, nanosensing of biomolecules, or noninvasive thermotherapy in medicine. Most of […]