Catalysis in industry is often driven by empirical investigations and, eventually, by unexpected discoveries. Frequently, the scientific understanding of the process takes much longer to develop. Ideally, it would be preferable to reverse this timeline, where scientific insights precede application. Nonetheless, even when the scientific explanation takes more time, a deep understanding of the underlying […]
Carbon monoxide (CO) oxidation (2CO + O2 → CO2) on platinum (Pt) group metal surfaces is the model heterogeneous gas/surface catalytic reaction. Pt itself is of the upmost importance as a catalyst for car exhaust cleaning or for the water gas shift reaction, whereas Pt crystal surfaces are model systems for investigating the catalytic CO […]
Global energy demand is expected to rise around 30% by 2040 according to the International Energy Agency (IEA). Hydrogen (H2) produced by the electrolysis of water, using renewable electricity, the so-called green hydrogen, has emerged as a promising energy vector to respond to this increasing energy demand with the potential to decarbonize transportation, heating, and […]
Global energy demand is expected to rise around 30% by 2040 according to the International Energy Agency (IEA). Hydrogen (H2) produced by the electrolysis of water, using renewable electricity, the so-called green hydrogen, has emerged as a promising energy vector to respond to this increasing energy demand with the potential to decarbonize transportation, heating, and […]
Just like our hands, certain organic molecules relate to each other like an image and its reflection – a phenomenon that chemists call “chirality” or “handedness”. The two mirror images of the same molecule, namely both enantiomers, often possess different biological properties. This is key, for example, for drug discovery, as many times only one […]
C-H bond The emission of methane, a highly potent greenhouse gas, is escalating due to livestock farming and the ongoing thawing of permafrost. Converting methane and longer alkanes into more benign and valuable chemicals presents an opportunity to mitigate these hazards while providing a vast resource for the chemical industry. Nevertheless, the conversion of methane […]
Catalysis • Chemistry • DIPC Electronic Properties • DIPC Interfaces • Materials
Organic compounds of sulphur that contain the group -S- linked to two hydrocarbons are known as thioethers. This alternative name to sulphides comes from the fact that they are analogues of ethers in which the oxygen is replaced by a sulphur; thioethers are generally more reactive than ethers, though. The formation of thioether structures increases […]
Ammonia (NH3), a ubiquitous compound, was generated in excess of 187 million tons globally in 2020. Roughly 85% is employed in the creation of nitrogenous fertilizers, while the remainder is used for refining petroleum, producing various other chemicals, and manufacturing synthetic fibers like nylon. However, these processes come with a substantial energy expenditure. Presently, the […]
A catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change. The study of enzymes has provided us many of the prototypical concepts of catalysis, including the idea that a catalyst lowers the barrier to reaction and thereby accelerates the approach to chemical equilibrium, without altering […]
Catalysis • Chemistry • DIPC Biochemistry • DIPC Photochemistry
When we consider the concepts metal and catalysis, we tend to assume quite matter-of-factly that the metal will be the catalyst. This assumption is based on the fact that metals can be found in reactions where they act as catalysts or co-catalysts in the form of coordination and organometallic compounds, nano-sized or bulk materials and […]