Applicability or some usefulness is the mantra of new I+D research. However, in trying to obtain results or confirm an application we often forget to check or study the conditions and methods used. One example could be the different methodologies that we can be used to define antioxidant capacity. An antioxidant is a molecule that […]
A class of materials of utmost fundamental and applied interest is that of semicrystalline polymers. Actually, all solid synthetic polymers are, in general, partly crystalline and partly amorphous. The degree of crystallinity depends on the polymer structure and on how the solid is prepared. Rapid cooling of the molten polymer favors formation of an amorphous […]
The scattering of conduction electrons in metals owing to impurities with magnetic moments is known as the Kondo effect, after Jun Kondo, who analysed the phenomenon in 1964. This scattering increases the electrical resistance and has the consequence that, in contrast to ordinary metals, the resistance reaches a minimum as the temperature is lowered and […]
Biomedicine • Chemistry • Condensed matter • DIPC Photochemistry
Metal complexes are typically regarded as catalysts that convert organic substrates into more valuable compounds; however, to date, catalytic transformations of metal complexes are practically unknown and represent a complete new way of thinking in catalysis. Their development can expand the scope of bioorthogonal chemical reactions to inorganic substances and metal-based prodrugs, fostering the creation […]
Both the depletion of fossil fuels and the environmental concerns are a powerful drive for the development of sustainable routes to commodity chemicals. Lignocellulose, comprised of lignin, cellulose and hemicellulose, is the ideal candidate, but its inherent complexity hampers its transformation to value-added chemicals. The group of Katalin Barta at the University of Groningen has […]
Imagine a bucket filled with hard spheres. As these spheres are free to pack together as closely as geometry allows they tend to adopt a close-packed structure, a structure in which there is least unfilled space. X-ray diffraction studies reveal that many metallic elements have close-packed structures. This simple fact explains a couple of very […]
In ‘Chemistry Essentials for Dummies‘, John T. Moore writes: Matter is anything that has mass and occupies space. It can exist in one of three classic states: solid, liquid, and gas. When a substance goes from one state of matter to another, the process is called a change of state, or phase change. As he […]
We usually think of crystals as composed of different atoms in certain proportions, this proportion being the molecular fórmula that represents the crystal. However, it is not surprising that any molecule could be the basis of a crystal structure, whether a simple molecule such as methane, or a complicated molecule such as a protein or […]
Graphene is a two-dimensional allotrope of carbon made of hexagons. It is a zero-gap semimetal with a tiny overlap between valence and conductance bands. Since the isolation of graphene in 2004, considerable interest has been paid to exploring its applications in a variety of fields such as electronics, composites, sensors, catalysis and energy related systems […]
Among the group 13 elements, boron alone forms halides of the type X2B-BX2 (X=F, Cl, Br, I), known as tetrahalodiboranes. Over the past five years, the filing of patents involving tetrahalodiboranes has outpaced their appearance in journal articles at a rate of two to one, mostly due to the current interest in B2F4 for the […]