As candidates for high-density data storage and quantum computation, magnetic transition metal complexes have attracted extensive attention. It has been established that the atomic surroundings of the magnetic ions play a significant role and govern the magnetism of these magnetic complexes. One feature in particular, magnetic anisotropy, which describes the preferential orientation of the magnetic […]
A catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change. The study of enzymes has provided us many of the prototypical concepts of catalysis, including the idea that a catalyst lowers the barrier to reaction and thereby accelerates the approach to chemical equilibrium, without altering […]
One-dimensional metal−organic chains often possess a complex magnetic structure, susceptible to modification by alteration of their chemical composition. The possibility to tune their magnetic properties provides an interesting playground to explore quasi-particle interactions in low-dimensional systems. These systems have potential applications in the fabrication of nanodevices for spin sensing, spintronics, quantum computing based on the […]
Graphene is an exceptional material with attractive properties to explore fundamental physics and for use in technological applications. While ideal graphene is non-magnetic, custom-shaped graphene nanostructures can be designed to exhibit complex magnetic phenomenology, with promising possibilities for a new generation of nanoscale spintronics devices. In fact, graphene π magnetism is more delocalized and isotropic […]
An atomic projectile colliding with a surface at kinetic energies in the thermal or hyperthermal range interacts with and is reflected by the electronic density well in front of the first layer of target atoms, and it is generally accepted that the repulsive interaction potential is proportional to the density of electrons extending outside the […]
Graphene nanoribbons (GNRs), are strips of graphene with ultra-thin width (<50 nm). Graphene ribbons were introduced as a theoretical model by Mitsutaka Fujita and coauthors to examine the edge and nanoscale size effect in graphene. Now, a team of researchers reports the generation of net spins on chiral GNRs (chGNRs) by ketone functionalization. GNRs are […]
When talking about molecules, “open shell” signifies that there are unpaired electrons. In terms of molecular orbital theory, it means that some molecular orbitals are singly occupied. Organic open-shell compounds are extraordinarily attractive materials for their use in molecular spintronics. In spintronics, new memory and logic devices are being developed based on the use of […]
A quasicrystal is a solid structure in which there is long-range incommensurate translational order and a long-range orientational order with a point group. Translated, this simply means that a quasicrystal is ordered but not periodic and, still, it can fill space completely. In two dimensions, the fivefold symmetry of a pentagon is an example of […]
In the last decades, a mathematical description of symmetries in nature called topology has been applied to describe and predict new electronic and magnetic properties of materials. A very simple aspect of topology connects a symmetry in the atomic structure of a crystal with a class of materials. Many materials that we know or use […]
Tetrapyrroles,“the pigments of life”,are key molecules for the metabolism of living organisms, supporting functions of vital importance such as electron transport, light-harvesting and oxygen reduction. Within this family of compounds, porphyrins are organic pigments characterized by the possesion of a cyclic group of four linked nitrogen-containing rings called porphyrin, the nitrogen atoms of which are […]