Category archives: Chemistry

Riboflavin as a bioorthogonal photocatalyst

Riboflavin as a bioorthogonal photocatalyst

ChemistryCondensed matterDIPC BiochemistryDIPC PhotochemistryPharmacy

By DIPC

The combination of catalysis and bioorthogonality promises have an impact on drug discovery and bioimaging. Bioorthogonality, a term coined by Carolyn R. Bertozzi in 2003, refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. Hence, catalytic turnover can boost the efficiency of bioorthogonal chemical reactions, unveiling […]

Strong donor-acceptor coupling does not require covalent bonding

Strong donor-acceptor coupling does not require covalent bonding

ChemistryCondensed matterMaterialsQuantum physics

By DIPC

Interfacial electron transfer constitutes the key step in the conversion of solar energy into electricity and fuels. Required for fast and efficient charge separation, strong donor−acceptor interaction is typically achieved through covalent chemical bonding…or not. Experiences with donor−acceptor molecular diads and triads, conjugated polymers, and DNA, leads to the expectation that a covalent bonding is […]

Recovering native chemical information from surface-enhanced Raman scattering

Recovering native chemical information from surface-enhanced Raman scattering

ChemistryCondensed matterPhysicsQuantum physics

By DIPC

For centuries, metals were employed in optical applications only as mirrors and gratings. New vistas opened up in the late 1970s and early 1980s with the discovery of surface-enhanced Raman scattering and the use of surface plasmon (collective electronic oscillations at the surface of metals) resonances for sensing. However, it was not until the 1990s […]

Geological phenomena implying dissolved species bring new insights on fundamental thermophysics

Geological phenomena implying dissolved species bring new insights on fundamental thermophysics

ChemistryCondensed matterGeosciences

By DIPC

Over geologic time scales, seawater transforms the basalt of the ocean floor by chemical attack. At the end of this alteration process, the basalt turns partly into clays and partly into dissolved salts in sea water. Lithium, a chemical element initially contained in basalt, will then be distributed between clay and seawater. This separation has […]

Enantioselective polymerization of a biodegradable polymer using a substituted aminoacid as a catalyst

Enantioselective polymerization of a biodegradable polymer using a substituted aminoacid as a catalyst

ChemistryCondensed matterMaterials

By DIPC

The idea that certain natural products such as rubber are composed of giant molecules, or polymers, consisting of many repeating units linked by covalent bonds arose largely from the work of the German chemist Hermann Staudinger (1881–1965) in the early 1920s. He convinced skeptical chemists of this idea partly by linking small organic molecules (monomers) […]

Combatting antimicrobial resistance with a ruthenium-based photorelease antimicrobial therapy

Combatting antimicrobial resistance with a ruthenium-based photorelease antimicrobial therapy

ChemistryCondensed matterMedicineMicrobiologyPharmacy

By DIPC

Antimicrobial resistance is a complex problem that contributes to health and economic losses worldwide. Resistance to antimicrobial therapies reduces the effectiveness of current drugs, leading to increased morbidity, mortality, and health care expenditure. Because globalization increases the vulnerability of any country to diseases occurring in other countries, resistance presents a major threat to global public […]

Plasmons galore for myriad applications

Plasmons galore for myriad applications

ChemistryCondensed matterMaterialsNanotechnologyPhysicsQuantum physics

By DIPC

Worldwide research efforts on plasmons and metamaterials have been growing exponentially for the past ten years. Now, Antonio I. Fernández-Domínguez (IFIMAC), Francisco J. García-Vidal (IFIMAC & DIPC), and Luis Martín-Moreno (ICMA) discuss new directions for the future, such as the use of 2D materials and strong coupling phenomena, which are likely to shape the field […]

How to study magnetic Weyl fermions experimentally

How to study magnetic Weyl fermions experimentally

ChemistryCondensed matterQuantum physicsTheoretical physics

By DIPC

Imagine there exist a material in which an electron could be split into two quasiparticles. These two quasiparticles both would carry electric charge, move in opposite directions but could not move backwards. Furthermore these quasiparticles would be massless. And we can give them a fancy name, Weyl fermions. This seems to be at odds with […]