Nature is a source of inspiration for scientists. If the efficiency of natural processes efficiency has been honed by billions of years of evolution, it seems reasonable that the best way to achieve some process is to try and mimic what nature has already come up with. This is the case with photosynthesis, a process […]
Organic chemistry uses lots and lots of names. Not only purely chemical names, but people’s names. This is so because the field is so broad that you need to name not only substances, that usually have two names, the official – from IUPAC rules – and the nickname, usually much shorter and easier to remember […]
Planes, ships, trucks and (most) cars run on different fractions of crude oil, composed of carbon chains of different length: Diesel (C 10 -C 22 ), kerosene (C 8 -C 16 ) and gasoline (C 5 -C 12 ). Despite their current supremacy, it is well known that fossil fuels will not be the energy […]
Molecular recognition is a critical process for many biological functions and consists in non-covalent binding of different molecules, such as protein-protein, antigen-antibody and many others. The host-guest molecules involved often show a shape complementarity, and one of the leading specification for molecular recognition is that the interaction must be selective, i.e. the host should strongly […]
A catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change. As the catalyst itself takes part in the reaction it may undergo a physical change. Hence, if catalysts take the form of nanoparticles, any physical feature of the nanoparticle interacting with the reacting molecules may […]
Some heteropolymers can be designed to spontaneously self-assemble in complex pre-determined knotted structures. In the past, we referred to such designable heteropolymers as “bionic proteins”. Here we present an extensive study on self-knotting bionic proteins. As our everyday experience with ropes teaches us, knots form spontaneously in polymer chains of sufficient length and flexibility have […]
Chemistry • Condensed matter • Materials • Nanotechnology • Quantum physics
A quantum dot is a nanometric crystalline structure of semiconductor materials. In a quatum dot electrons are confined in a region of space, thus creating a well defined structure of energy levels that depends very much on the size and shape of the quantum dot. This structure resembles that of atoms, that is why sometimes […]
In the transition from a petrol-based society to a one based on bio-renewable resources, the replacement of aromatic chemicals is one of the most challenging issues. Nowadays, around 40% of the bulk chemicals belong to the aromatic category, and a myriad of products are derived from benzene, toluene and xylene. Aromatic molecules are present in […]
When nanoparticles (NPs) get in contact with biological fluids such as blood, proteins present in it will adsorb on the surface of those NPs forming what is known as the protein corona . It is a dynamic process in equilibrium with the surrounding proteins and it may lead to drastic changes in the NPs. The […]
Endohedral fullerenes, also called endofullerenes, are fullerenes that have additional atoms, ions, or clusters enclosed within their inner spheres. The first lanthanum C60 complex was synthesized in 1985 and called La@C60. The @ (at sign) in the name reflects the notion of a small molecule trapped inside a shell. The chemistry of endohedral fullerenes is […]