Category archives: Chemistry

Investigating the fundamental stages of the CO oxidation reaction using a kinked Pt crystal

Investigating the fundamental stages of the CO oxidation reaction using a kinked Pt crystal

Catalysis • Chemistry • DIPC Interfaces

By DIPC

Carbon monoxide (CO) oxidation (2CO + O2 → CO2) on platinum (Pt) group metal surfaces is the model heterogeneous gas/surface catalytic reaction. Pt itself is of the upmost importance as a catalyst for car exhaust cleaning or for the water gas shift reaction, whereas Pt crystal surfaces are model systems for investigating the catalytic CO […]

Synthesis of organometallic helicenes by simple combinations

Synthesis of organometallic helicenes by simple combinations

Chemistry • DIPC Biochemistry • Materials

By DIPC

“Helicene” is the name introduced by Newman in 1955, to describe the benzologues of phenanthrene in which the extra ortho -condensed rings give rise to a (regular) cylindrical helix. The pioneer work of Newman in this field cannot be overemphasized; his brillant synthesis and resolution of [6]helicene will remain as a landmark, for it opened […]

Stable, high-energy-density and fast charging lithium-ion batteries

Stable, high-energy-density and fast charging lithium-ion batteries

Chemistry • Materials

By César Tomé

Convenient fast charging and energy density of lithium-ion batteries have long been considered a trade-off, which has hindered the widespread adoption of electric vehicles. A new process will help develop stable, high-energy-density lithium-ion batteries capable of fast charging. A crucial prerequisite for the widespread adoption of electric vehicles (EVs) is the enhancement of lithium-ion battery […]

Triple-decker antiaromatic π-stacking leads to a liquid crystal

Triple-decker antiaromatic π-stacking leads to a liquid crystal

Chemistry

By César Tomé

In organic chemistry, π-stacking systems are supramolecular structures that arise due to the dispersion force, a type of intermolecular noncovalent interaction. They are a common occurrence in nature. The stabilized structure of DNA is a very prominent example of a π-stacking system, and so are the arrangement of amino acids in certain proteins. Interestingly, π-stacking […]

A closer look at peptide fibril assemblies

A closer look at peptide fibril assemblies

Biochemistry • Biology • Chemistry • Nanotechnology

By César Tomé

A new imaging technique can give scientists a much closer look at fibril assemblies, stacks of peptides like amyloid beta, most notably associated with Alzheimer’s disease. These cross-β fibril assemblies are also useful building blocks within designer biomaterials for medical applications, but their resemblance to their amyloid beta cousins, whose tangles are a symptom of […]

Extracting lithium from waste liquids using aluminium hydroxide

Extracting lithium from waste liquids using aluminium hydroxide

Chemical engineering • Chemistry • Energy • Materials

By César Tomé

A team of researchers has invented a more efficient way to extract lithium from waste liquids leached from mining sites, oil fields and used batteries. They demonstrated that a common mineral can adsorb at least five times more lithium than can be collected using previously developed adsorbent materials. The new low-cost high-lithium-uptake process presents the […]

The stabilizing effect of a binder for transition metal oxides to sustain water oxidation in acidic environments

The stabilizing effect of a binder for transition metal oxides to sustain water oxidation in acidic environments

Catalysis • Chemistry • DIPC Advanced materials • Materials

By DIPC

Global energy demand is expected to rise around 30% by 2040 according to the International Energy Agency (IEA). Hydrogen (H2) produced by the electrolysis of water, using renewable electricity, the so-called green hydrogen, has emerged as a promising energy vector to respond to this increasing energy demand with the potential to decarbonize transportation, heating, and […]

Efficient on-surface Ullmann-like reaction on poorly reactive surfaces

Efficient on-surface Ullmann-like reaction on poorly reactive surfaces

Chemistry • DIPC Electronic Properties • DIPC Interfaces

By DIPC

The way a particular reaction proceeds, described in terms of the steps involved, is called mechanism. The study of organic chemistry is, to a great extent, the study of reaction mechanisms and textbooks content both their description and their applications. But something has come to revolutionize the world of mechanisms: surface chemistry. On-surface synthesis is […]